First check the location where you found it. If it was near cultivated farmland, then there's a risk that it's been in contact with pesticide or chemical fertiliser, so I wouldn't use it.
However, if youre confident that it can't have come into contact with harmful chemicals, then I'd do the following if it won't fit in the oven....
First strip the bark off, as this is where the creepy crawly population will mainly be living.
Then get some reptile-safe disinfectant, dilute it according to the instructions and put it in a plant misting bottle.
Rinse your bath so there are no traces of shampoo, soap, bubblebath etc.
Put the branch in the bath and spray liberally with the reptile disinfectant until it is thoroughly soaked.
Leave for an hour, turn the branch over and do the same.
Leave for an hour, then boil the kettle and pour boiling water all over the branch (while still in the bath!). May take several kettles-ful of water to do the whole thing.
Rinse the branch well with a shower if you have one, just to make sure that all traces of disinfectant are cleared.
Leave the branch to dry for a few days.
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